Reactions and Syntheses of Pyrazines

Catalytic enantioselective Strecker reactions and analogous syntheses.

3.1. Overview 2807 3.2. Chiral Aluminum(III) Complexes as a Catalyst 2808 3.2.1. Aluminum(III)-Salen-Based Catalysts 2808 3.2.2. Aluminum(III)-Binaphthol-Based Catalysts 2810 3.3. Chiral Titanium(IV) Complexes as a Catalyst 2814 3.3.1. Titanium(IV)-Peptide-Based Catalysts 2814 3.3.2. Titanium(IV)-Diol-Based Catalysts 2817 3.4. Chiral Zirconium(IV) Complexes as a Catalyst 2818 3.4.1. The Catalyt...

SYNTHESES AND REACTIONS OF PYRAZINE AND QUINOXALINE 1.1 Pyrazine

Dialkylboron guanidinates: syntheses, structures and carbodiimide de-insertion reactions.

The synthesis of novel dialkylboron guanidinates is reported: the symmetrical compounds, (Me2N)C(NR)2BR'2 [R = iPr, R' = Nrb (1); R = Cy, R' = Nrb (2); R = iPr, R' = Cy (3); R = R' = Cy (4); R = 2,6-iPr2-C6H3; R' = Cy (5); Nrb = exo-2-norbornyl] and the asymmetrically coordinated {iPr(H)N}C(NiPr)(NAr)BCy2 [Ar = Ph (6), 4-Me-C6H4 (7), 4-tBu-C6H4 (8)] were prepared by the salt metathesis method f...

Phosphorus peri-bridged acenaphthenes: efficient syntheses, characterisation and quaternization reactions.

Using a novel strategy, tertiary phosphines based on single atom peri-bridged acenaphthenes were prepared and characterized by multinuclear NMR and by X-ray diffraction.

Syntheses of α-Pyrones Using Gold-Catalyzed Coupling Reactions

Sequential alkyne activation of terminal alkynes and propiolic acids by gold(I) catalysts yields compounds having α-pyrone skeletons. Novel cascade reactions involving propiolic acids are reported that give rise to α-pyrones with different substitution patterns.